Το έργο “Έρωτας και Ψυχή”, φιλοτεχνημένο κατά το α’ μισό του 19ου αιώνα από άγνωστο καλλιτέχνη, έχει διπλή αξία: από τη μια πρόκειται για ένα αριστουργηματικό έργο, που αντανακλά τη διαχρονικότητα της ομώνυμης μυθολογικής αλληγορίας, και από την άλλη, έχει ιστορική σημασία για την Εθνική Πινακοθήκη, αφού αποτελεί ένα από τα 117 έργα, που συγκρότησαν τον πρώτο πυρήνα της συλλογής της (δωρεά του Πολυτεχνείου).
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